How to Mix Oil Paints - The Color Wheel

Updated: 17 Oct 2018

Titanium white oil paint by Maimeri

Intro

A major component of oil painting is the knowledge of how to mix oil paints and understanding the relationships within the color wheel.

The ability to match the right color in the right brightness is essential for realism or impressionism painting.

What are Oil Paints and Pigments?

Light:

Light is a collection of energy-particles (photons) that travel in waves.

Sensors in the human eye can detect some wavelengths and the human brain translates different wavelengths as different colors.

When light that consists of all the detectable wavelengths reach the eye, like from looking at the sun or a lamp, the human brain will translate it as white or yellowish white.

Therefore, colors are a characteristic of the human sight, meaning the translation of different wavelengths to different colors.

Pigment:

A pigment is a substance or material that absorbs a portion of the visible wavelengths and reflects the rest.

Chlorophyll, for example, is a pigment that exists in plants and is essential for photosynthesis.

The Chlorophyll pigment absorbs many wavelengths but reflects the wavelengths we translate as green. That is the reason we see plants as if they are green.

In other words, a pigment is a substance that changes the color of light by selective absorption of wavelengths.

Oil paints:

Oil paints are pigments (dry powder), mixed with a binder, usually linseed oil.

Oil based paints do NOT dry; they become solid. When linseed oil meets oxygen from the air, the process of oxidation begins (absorption of oxygen atoms) and Polymerization (oil molecules react to form polymers, which are huge molecules).

Oil Paint Characteristics

Opacity: Transparent vs Opaque

Oil paints have different levels of opacity.

Oil colors labeled as opaque will cover the canvas completely.

Oil colors labeled as semitransparent or transparent will cover the canvas, or the under layer of paint, partially.

Oil paints opacity, Transparentand and opaque colors

Warm and Cool Colors

Most oil paints are not pure colors, but a bit warm or cool.

For example: Cadmium Yellow is a warmer yellow because it is a bit orange, while lemon yellow is a cooler yellow because it is a bit greenish.

Another example: Cadmium red is a warmer red, meaning it is an orange red, while quinacridone red is a cooler red because it has a purple tinge.

Warm and cool yellow colors Warm cadmium vs cool lemon
Warm and cool red colors Warm cad vs cool quinacridone

Yellow, for example, will always be warm but some yellow colors will be warmer while other yellow colors will be less warm.

THE COLOR WHEEL: Primary Colors

There are 3 primary colors:

A primary color is a color that cannot be mixed from other colors. Therefore, it is necessary to buy all three primaries.

Blue Pigment

Blue oil paint can be:

Blue oil paints: Ultramarine and Cobalt Purple tinge Ultramarine blue
Neutral Cobalt blue
Blue oil paints: Phthalo, Prussian and Cerulean Blue oil paints with a green tinge:
Cerulean, Prussian and Phthalo

*Phthalo blue is a staining color, meaning even after washing the brushes, they will stay with a greenish blue tinge. It is a dominant color and it has a very strong scent.

Azure (Sky blue) is a mixture of blue and white pigments.

Red Pigment

Red is a dominant color and therefore it is used for important traffic signs. In text, red symbolizes warning.

Since red captures the attention of the viewer, it is best to avoid it (in landscape paintings) for parts in the painting that are far.

Pink is a mixture of red and white pigments. Adding a bit of yellow to pink will create peach color.

Red oil paints: quinacridone and alizarin crimson Cool red oil paints
Alizarin crimson and quinacridone
Pink oil paints, mixture of red and white pigments Pink color palette
Mixture of red and white

Yellow Pigment

Yellow is a bright color, which is sometimes used for brightening other colors.

Yellow ochre (also ocher) is one of the ancient earth colors and it has many uses.

Yellow oil paint pigment palette Yellow oil paints palette
yellow ochre, ocher oil paint pigment Yellow Ochre oil paint

THE COLOR WHEEL: Secondary Colors

There are 3 secondary colors:

The 3 primary colors can be used to mix the 3 secondary colors:

Color wheel with 3 primary oil paints The 3 primary colors
Color wheel with primary & secondary colors Mixing the 3 secondary colors

Purple Pigment

Purple is the mixture of red and blue.

Cool red oil paints, like quinacridone or alizarin crimson, are best for mixing purple. Warm red oil paints, like cadmium red, will produce brownish or grayish purple.

Mixing red & blue to create purple oil color Mixing red and blue makes purple
Purple pigment oil paints color palette Purple oil paints palette

Purple color can be very dark. Adding a bit of white will make it lighter.

Green Pigment

Green is a mixture of blue and yellow.

Mixing black and yellow will produce a khaki green.

Mixing blue and yellow for green Yellow and a bit of blue
Mixing black and yellow for khaki green Yellow and a bit of black

Orange Pigment

Orange is a mixture of red and yellow.

Mixing red and yellow pigments for orange Red and yellow mixed
Orange pigment oil paints color palette Orange oil paints color palette

Orange mixed with white can be used as a basis for light skin tone.

For less saturated orange, it is possible to add a bit of the opposite color (blue) to the mixture.

Realistic oil painting of an orange origami boat Still life oil painting, 80/50cm: Origami boat. Quinacridone red & cadmium yellow.

Colors with high saturation:

There are some cases in nature or in objects which are man-made that have high saturation.

In these cases, the color cannot be mixed from other colors. Therefore, buying a specific oil paint tube is the only solution.

These specific colors can be regarded as primary colors since they too cannot be mixed.

THE COLOR WHEEL: White, Black and Gray

White Pigment

White pigment does not absorb any wavelength (color); it reflects them back. Since all the other colors absorb some wavelengths, they cannot be used to mix white. Thus, it is necessary to buy white oil paint.

White is an important color and the main color for lightening other colors.

Pure white is rarely seen in nature, due to reflections and other factors. In most cases, it is best to avoid the usage of pure white while painting.

There are three main white oil paints that are composed of two pigments: Titanium (PW6) and zinc (PW4).

White oil paints: Flake, Titanium and Zinc The 3 main white oil paints:
Flake, titanium, zinc
Blue oil paints color palette Blue oil paints palette:
Adding white for lighter values

Black and Gray Pigments

Black is the darkest color. It absorbs all wavelengths. There are many ways to mix black from other colors.

Mixing all 3 primaries (~x yellow, 2x red, 4x blue) will create black. That is like mixing a very dark purple and then adding a bit of the opposite color, yellow.

Ultramarine blue mixed with burnt umber is a cheap and fast way to create black. Most brown or orange oil paints can be mixed with most blue oil paints to form different blacks.

Gray is adding a bit of white to black. A bit more brown will create a warm gray and a bit more blue will create a cool gray.

Mixing all 3 primary colors to create black All 3 primaries mixed together
Adding white to create gray
Mixing ultramarine blue & burnt umber for black. Adding white to create gray. Ultramarine blue & burnt umber
Adding white to create gray

Something to consider:

While all colors reflect different amount of wavelengths, black absorbs all and does not reflect anything. This can look a bit strange on a painting, as if there are "holes" in the painting where black is painted.

The solution is to mix black paint from other colors and not to buy black oil paints, even though they are very cheap. It is a matter of personal preference.

Highlight and Shadow

The color wheel

Every object is made of pigments, which define its color.

The area of an object that is in front of a light source is called highlight and the area that is hidden from the light source is called shadow.

Highlight:

The highlight area can be lighter, brighter or both.

For light color, which is less saturated, add white to the mixture.

For bright color, meaning saturated color, look at the color wheel and add the next color toward yellow.

Often, highlight means light and bright color.

Shadow:

For the shadow area, it is possible to add a bit of the opposite color in the color wheel.

Adding the opposite color, will darken the color and make it less saturated.

Opposite colors are pairs of primary and secondary colors. A secondary color is a mixture of 2 primary colors. Therefore, mixing opposite colors is a mixture of all 3 primaries.

Mixing all 3 primary colors will absorb most of the wavelengths and will result in a darker color.

Using the opposite color in the color wheel is a shortcut for mixing shadow area colors. In reality, the shadow is influenced by a multitude of factors.

Highlight and shadow summary:

When drawing and painting nature in a realistic style, the objects will be less saturated.

Some flowers under a certain climate or some man-made object will be very saturated.

For most paintings, all the colors, including highlights and shadows, can be mixed from the three primary colors and white.

For special cases of saturated objects, under a certain light, a tube of a specific oil paint might be needed.

The color to be mixed and used will be defined by observation, knowledge and experience.

THE COLOR WHEEL: Complementary Colors

The color wheel is an arrangement of colors around a circle, which enable to see the relationships between the three primary colors and the three secondary colors.

Opposite colors, cancel each other when mixed, forming a brown or gray color.

The opposite color of each color in the color wheel, which can be used to mix shadow color, is also the complementary color.

Complementary colors, when painted next to each other, form the strongest contrast and look well together.

Painting a red apple, for example, will look well with a green background.

Opposite or complementary colors used by Disney. Complementary colors used by Disney

Leonardo da Vinci noticed that some pairs of colors produce the best harmonies.

There was no scientific explanation for that until some two hundred years after his death, when Sir Isaac Newton, in his research on optics, created a wheel that shows the colors of the spectrum and that the opposite colors create the most obvious contrast.

THE COLOR WHEEL: Earth Colors

Earth colors include three main pigments: Umber, Sienna and Ocher.

Umber comes as Raw Umber or Burnt Umber.

Sienna comes as Raw Sienna or Burnt Sienna and has a red or orange tinge.

Yellow Ocher pigment is also associated with the yellow family.

These pigments are suitable for landscape painting, hair painting and more.

Raw & burnt Umber oil pigments Raw Umber & Burnt Umber
Raw & burnt Sienna oil pigments Raw Sienna & Burnt Sienna

All earth pigments contain iron oxide. In addition to Iron Oxide, Umber and Sienna pigments contain manganese oxide.

Oxide is a compound, of a substance or an element, with oxygen. Iron oxide is the reason for the red-brown color of rust and the red color of blood.

Earth colors are the oldest and most durable pigments. Today, earth colors also exist as synthetic pigments.

The 3 main earth pigments:

PY43 (Pigment Yellow 43)

Pigment representing natural yellow ocher and natural Raw Sienna.

Pigment PY42 represents the synthetic alternative.

PR102 (Pigment Red 102)

A pigment representing natural Burnt Sienna and many more browns and reds such as Mars Brown, Terra Rosa and Venetian Red.

Pigment PR101 represents the synthetic alternative.

PBr7 (Pigment Brown 7)

Pigment representing natural Burnt Umber, natural Burnt Sienna and many other browns.

Pigment PBr6 represents the synthetic alternative.

How to Mix Brown

In addition to earth colors, it is possible to mix brown color from other colors.

Mixing the opposite colors of the color wheel will result in brown. Adding a bit of the opposite primary color to the secondary color: a bit of blue to orange, a bit of yellow to purple or a bit of red to green will result in brown oil paint.

Another way is to mix all 6 primary and secondary colors together to form a basic brown. From that basic brown, it is easy to mix the other brown colors. Adding a bit of red to the basic brown will create Burnt Sienna, adding a bit of yellow will create Yellow Ocher and so on.

Mixing all 6 primary & secondary colors Mixing all 6 colors
Mixing orange with a bit of blue for brown Mixing orange with a bit of blue

Something to consider:

Since earth pigments are cheap compared to the primary colors, it is advised to buy brown oil paint and not mix it.

Oil Paints Types

Oil paints are usually a mixture of oil with a single pure pigment or a mixture of several pigments, but there are other types:

Hue:

The mark Hue on a paint tube means that the specified pigment is NOT the actual pigment. In some cases, when a specific pigment is toxic or expensive, a combination of other pigments can produce a similar result in a safer or cheaper way.

A good example is the Lead or Flake White, which was toxic and is produced today from safer pigments, but keeps its name with the addition of the word Hue.

I.e. Flake White (Hue).

Lake:

The mark Lake on a paint tube is the use of dye, which was made solid instead of ground minerals for example. In some cases, these oil colors will be less lightfast*.

*Lightfastness of a pigment or a dye means how resistant it is to direct light and how long it will be before the color will start to fade.

Flake White Hue oil paint pigment Hue
Green Lake oil paint made of dye Lake

How to Choose Oil Paints

Most of the leading brands of oil paints hold at least two grades of colors:

Which brands of oil paints to choose from:

The main importance of colors for oil painting is the ability and knowledge to mix the right colors and the correct brightness level. There is less importance to the type of brand or type of pigment; it is a matter of personal preference.

Keep in mind:

When opening a new tube of oil paint, if there is oil leaking on the work surface, it is, usually, a good sign. That means there are only pigments and oil in the tube.

Some brands add a binder to the mix, which makes the oil paint less runny and therefore solvents/thinners should be added which is less idle.

How to Paint in Layers

Fat over lean principle:

Thinners or diluents are evaporating materials.

Mixing oil paints with a thinner makes them harden faster because there is less oil in the mixture.

When painting in layers, each new layer will have a bit more oil and a bit less thinner.

A new layer may slightly block the air for the lower layer and thus slow down its hardening process. In this situation, the upper layer will harden before the lower layer and when the lower layer hardens, it may damage the hard top layer and crack it.

The top layer should be fat, meaning with a larger amount of oil thus harden slowly. The lower layer should be lean, meaning less oil and more thinner, making it harden faster.

In addition, there is a claim that a larger amount of oil will cause the layer to be more flexible and therefore less likely to crack.

Color Palettes

Color palettes can be prepared in advance for future reference and usage.

Each pigment should be mixed with an increasing amount of white pigment to create lighter versions.

Each 2 pigments should be mixed with one another and with an increasing amount of white to create different degrees of brightness.

The color palettes should be made from a material that is suitable for oil paints.

Oil paint color palette One pigment and white
Oil paint color palette Mixture of 2 pigments and white

An example for creating color palettes by the painter Thomas Baker:

Basic Terms for Color Theory

Note: Different artists or color theories use these terms quite loosely or in a different way.

For example, lightness, sometimes, refers to value or tone.

Summary

How to start:

One way is to use the 3 primary colors, brown and white.

With these 5 colors it is possible to mix most colors and shades.

When using a limited palette (red, yellow, blue, brown and white), white and yellow are used for lightening colors while brown and blue are used for darkening colors.

How to mix colors:

Mixing oil paints means to find the correct hue and the correct brightness value. That is to say how bright or dark the color mixture is compared to the brightness level of the observed object.

When dark or light colors are added to the mixture, the brightness values will change, and should be adjusted again until both the value and hue are accurate.

Colors can be pre-mixed with a palette knife or mixed with a paintbrush while working.

Color comparison:

When painting an object from observation or using a printed image, it is useful to hold a paintbrush or a palette knife with the mixed oil paint and place it next to the object or the reference image and check if the brightness level and hue are the same.

This will not work when comparing colors against a computer or TV screen because these devices have their own lighting that is different from the studio light.

It is a good idea to draw the color wheel (or print a picture of it) that will always be available.

Time spent on color mixing:

Mixing oil paints takes time.

For some painters, especially in a realism or impressionism painting style, mixing colors will be the main work and time spent compared to actual painting.

Oil paints and toxicity:

There are some toxic pigments, such as cobalt and cadmium, and it is best to use gloves in some cases. Hands should be washed before touching food.

Information about pigments

List of pigments